Polyimide Brief Introduction


Polyimide is a non-flammable fiber in atmospheric conditions. The LOl is above 38%. 

It is resistant to high and low temperatures and can be used for a long time below 300℃, with a thermal decomposition temperature of more than 567℃ and no brittle breakage in liquid nitrogen at -169℃.

Polyimide fiber will carbonize without melt and drop in case of fire. The density of smoke is 1/200 of the airbus requirement. 

Products made of Polyimide fiber also have other excellent properties such as weather resistance,thermal insulation,chemical resistance, radiation resistance,UV resistance.


NO

Item

Unit

Value

1

Fineness

dtex

0.8-6

2

Density

g/cm

1.41

3

Breaking strength

   cN/dtex   

   Nature clolor

>4.5   

   Dope dyeing

>3.5   

4

Modulus

cN/dtex

36~43

5

Breaking elongation

%

10~30

6

    Suggested long-term working temp    

260

7

Initialde composition temperature

(T5%(N2))

569

8

Limiting oxygen index(LOI)

%

38

9

Acid resistance

/

good

10

Radiation resistance

/

good



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Polyimide Performance Advantages


Flame retardant performance

The limiting oxygen index

The limiting oxygen index (LOI) refers to the minimum oxygen volume fraction required to maintain complete combustion in a mixture of oxygen and nitrogen. As a new generation of high performance fiber,Polyimide fiber has better flame retardant performance than traditional special fiber, with LOl up to 38%.


   Common flame retardant fiber   

   Polyimide   

   PMIA   

   PPS   

LOI (%)

>38

28~30

34


Low damaged length incombustion test

In vertical combustion test under Chinese fire protection criteria XF10-2014, the damaged length of Polyimide fabric is 1/5 of the aramid IIlA fabric (the mainstream FR fabric). The test result is far above the standard for protective fabric.


Damaged length
  (mm)

Polyimide

Aramid IIIA fabric

50%Polyimide

  50%FR viscose  

50% amaid

  50%FR viscose  

Standard

Flame retardant

properties (25times Wash)  

Warp

10

46

12

60

≤100

  Weft  

8

48

13

57


Smoke toxicity

Polyimide fiber will carbonize without melt and drop in case of fire.

FR fabric made of Polyimide fiber passed the combustion test based on BSS7238,7239. There is ultralow smoke and non-toxic after carbonization.

The density of smoke is1/200 ofABD0031 airbus requirement. According to the smoke density test method of building materials decomposition (GBT8627-2007),the smoke density grade(SDR) of pure Polyimide felt is only 0.12, far lower than the smoke density grade of current building insulation materials. 

Polyimide fiber is an wonderful material for confined space textiles, heat insulatin,home textile and protective products.

 

Polyimide fabric toxic comparison

Item

  Smoke density  
  (Dm)

Toxic gas content (unit:ppm)

  CO  

  HCN  

  HF  

  HCL  

  SO2  

  NOX  

Polyimide

1

32

0.7

<0.5

<1

<0.5

<2

  Airbus standard  

200

3500

150

100

150

100

100


High Temperature Resistance

The long-term service temperature of Polyimide fiber is up to 260~300℃. Initial decomposition starts from 567℃, As raw material of filter bag, the good dimensional stability and strength retention under high temperature provide higher filtration efficiency and service life.

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Weather Resistance and Chemical Resistance

Polyimide fiber has excellent resistance to radiation, acid, alkali and thermal oxidation.

It can keep outstanding mechanical property and chemical stability in the extreme environment such as space, sea, ice and desert.


Acid resistance

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Radiation resistance

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Salt spray test

Using 100% polyimide yarn in accordance with GJB150A-2009 standard for neutral salt spray test.


Item

   Unit   

   Initial State   

   After testing   

Breaking strength

CN

21*10²

19*10²

    Breaking elongation    

%

16

15


Antibacterial Property


Antibacterial function

Polyimide fiber has natural antibacterial function. The antibacterial effect outperforms bamboo fiber.


Test Item

Strain

   Standard   

    Result   

   Rate of Antibacteria   

   Staphylococcus Aureus   

≥70

98%

Colibacillus

≥70

99%

Candida albicans

≥60

99%

 

Fungus test

According to GJB150.10A-2009 laboratory environmental test method of fungus test showed that the Polyimide fabric without fungus growth.

Item

Test conditions

    Amount of growth    

    Rating    

    Polyimide yam    

    28days, humidity>90%RH    

temperature 30℃

None

0


Far IR Property

Far-infrared healthcare textile can promote blood circulation and metabolism,enhance immunity. 

Polyimide fabrics meet the national standard for the far-infrared healthcare product with a far infrared ray of 4~16μm and normal emittance of 88%.


Number

Test Item

    Standard    

    Result    

1

    Normal emission    

≥0.80

0.88

2

Wavelength

4~16

4~16

 

Thermal Insulation Property

As an effcient thermal insulation material, Polyimide fiber has a very low heat conductivity coefficient, and its thermal performance is higher than that of cotton, wool, silk and other traditional materials. 

The 210g/m’Polyimidefiber thermal insulation has a CLO value of 4.13 and a thermal resistance of0.64 m’·k/w, which is higher than that of 3M's Thinsulate™ with the same weight. It has been used in cold-proof clothing and quilts.


Category

    Weight(g/m)    

   Thickness(mm)   

   CLO   

   Thermal resistance   

(m*.k/w)

Polyimide

210

15.5

4.13

0.64

Thinsulate™G200

200

20

3.3

0.51

Thinsulate™ KL200

200

27

4

0.62

Thinsulate™KL250

250

33

4.6

0.71

Thinsulate™HZ250

250

33

4.3

0.67

    Thinsulate™ KZ200    

200

25

3.7

/

Thinsulate™Z250

250

27

4.0

0.62

 

Electrical Insulation Performance

The dielectric constant of polyimide is 3.4, and the corona resistance is good(parameter from the publically reported data of polyimide materials).


Color fastness

Polyimide solution dyed woven fabric has passed the colorfastness test and the results outperform the aramid one.


Item

Results

    Testing Method    

Color fastness to light

Grade 7

ISO105-B02

Color fastness to dry rubbing

Grade 4~5

ISO105-X12

Color fastness to wet rubbing

Grade 4~5

ISO105-X12

Color fastness to water

    Grade 4~5    

ISO105-E01

Color fastness to Acid perspiration

Grade 4~5

ISO105-E04

   Color fastness to alkali perspiration   

Grade 4~5

ISO105-E04

Color fastness to dry cleaning

Grade 4~5

ISO105-D01

Color fastness to washing

Grade 4~5

ISO105-C10


Healthy environment protection

Polyimide fiber is environmentally friendly from manufactur

ring to end use, and has passed Oeko-Tex® Standard 100, meeting EU textile import requiren ments.

 

Polyimide Fiber Application 


      High performance flame retardant protective clothing     

fire fighting clothing

special combat headgear

flight suit, ship damage control suit

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High performance insulation

         High-performance lightweight thermal filling material          

High thermal textiles

High performance insulation felt

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  High performance environmental protection filter material  

High temperature dust filter material

High-end automotive paint room filter material

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Composite materials

 High performance insulating paper

High performance honeycomb core material

Rubber reinforced material

High performance ablative material for solid rocket motors  

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